MULTICOMPONENT DETERMINATION OF CHLORINATED HYDROCARBONS USING A REACTION-BASED CHEMICAL SENSOR .3. MEDIUM-RANK 2ND-ORDER CALIBRATION WITH RESTRICTED TUCKER MODELS

A. K. Smilde; R. Tauler; J. M. HENSHAW; L. W. BURGESS; B. R. KOWALSKI

doi:10.1021/ac00092a010

MULTICOMPONENT DETERMINATION OF CHLORINATED HYDROCARBONS USING A REACTION-BASED CHEMICAL SENSOR .3. MEDIUM-RANK 2ND-ORDER CALIBRATION WITH RESTRICTED TUCKER MODELS

A. K. Smilde
, R. Tauler
, J. M. HENSHAW
, L. W. BURGESS
, B. R. KOWALSKI

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The calibration of a chemical sensor for chlorinated hydrocarbon analytes based on the Fujiwara reaction is described. This sensor generates a particular type of data: medium-rank second-order data. With this type of data it is possible to calibrate the sensor in such a way that quantitation for the analytes in the presence of unknown interferents is possible. The calibration method developed is a new approach based on so-called restricted Tucker models that utilize all available chemical information

Original language	English
Pages (from-to)	3345-3351
Journal	Analytical chemistry
Volume	66
Issue number	20
DOIs	https://doi.org/10.1021/ac00092a010
Publication status	Published - 1994

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@article{b1a3cd79a82840b69dbf8c27a1d3536a,

title = "MULTICOMPONENT DETERMINATION OF CHLORINATED HYDROCARBONS USING A REACTION-BASED CHEMICAL SENSOR .3. MEDIUM-RANK 2ND-ORDER CALIBRATION WITH RESTRICTED TUCKER MODELS",

abstract = "The calibration of a chemical sensor for chlorinated hydrocarbon analytes based on the Fujiwara reaction is described. This sensor generates a particular type of data: medium-rank second-order data. With this type of data it is possible to calibrate the sensor in such a way that quantitation for the analytes in the presence of unknown interferents is possible. The calibration method developed is a new approach based on so-called restricted Tucker models that utilize all available chemical information",

author = "Smilde, \{A. K.\} and R. Tauler and HENSHAW, \{J. M.\} and BURGESS, \{L. W.\} and KOWALSKI, \{B. R.\}",

year = "1994",

doi = "10.1021/ac00092a010",

language = "English",

volume = "66",

pages = "3345--3351",

journal = "Analytical chemistry",

issn = "0003-2700",

publisher = "American Chemical Society",

number = "20",

}

TY - JOUR

T1 - MULTICOMPONENT DETERMINATION OF CHLORINATED HYDROCARBONS USING A REACTION-BASED CHEMICAL SENSOR .3. MEDIUM-RANK 2ND-ORDER CALIBRATION WITH RESTRICTED TUCKER MODELS

AU - Smilde, A. K.

AU - Tauler, R.

AU - HENSHAW, J. M.

AU - BURGESS, L. W.

AU - KOWALSKI, B. R.

PY - 1994

Y1 - 1994

N2 - The calibration of a chemical sensor for chlorinated hydrocarbon analytes based on the Fujiwara reaction is described. This sensor generates a particular type of data: medium-rank second-order data. With this type of data it is possible to calibrate the sensor in such a way that quantitation for the analytes in the presence of unknown interferents is possible. The calibration method developed is a new approach based on so-called restricted Tucker models that utilize all available chemical information

AB - The calibration of a chemical sensor for chlorinated hydrocarbon analytes based on the Fujiwara reaction is described. This sensor generates a particular type of data: medium-rank second-order data. With this type of data it is possible to calibrate the sensor in such a way that quantitation for the analytes in the presence of unknown interferents is possible. The calibration method developed is a new approach based on so-called restricted Tucker models that utilize all available chemical information

U2 - 10.1021/ac00092a010

DO - 10.1021/ac00092a010

M3 - Article

SN - 0003-2700

VL - 66

SP - 3345

EP - 3351

JO - Analytical chemistry

JF - Analytical chemistry

IS - 20

ER -

MULTICOMPONENT DETERMINATION OF CHLORINATED HYDROCARBONS USING A REACTION-BASED CHEMICAL SENSOR .3. MEDIUM-RANK 2ND-ORDER CALIBRATION WITH RESTRICTED TUCKER MODELS

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